Showing posts with label Purging. Show all posts
Showing posts with label Purging. Show all posts

Saturday, August 29, 2009

Minimum Oxygen Concentration (MOC) for Flare Purge

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A fire is formed or a flame can sustains and propagate, three main elements shall present as defined in well known FIRE triangle. There are combustible material (or fuel), oxygen (O2) and heat. See following image. One additional characteristic shall also present is the potential of chain reaction to maintain continuous combustion before any of these three elements is removed. This speed of chain reactions define if a mixture is combustible (slow) or explosive (fast).

Minimum Oxygen Concentration (MOC)
Oxygen is common obtained from atmosphere. Standard air at Mean Sea Level (MSL) contains 20.95 vol% Oxygen (O2), 78.08 vol% Nitrogen (N2), 0.038 vol% Carbin Dioxide (CO2) and others inert gas i.e. Neon, Xenon, etc. Although Oxygen is the major component in generating fire, there is still a minimum oxygen concentration (MOC) required present in combustible mixture so that a fire can be initiated and propagated. Below this limit, a fire will not form.

Following MOC for some hydrocarbon common found in oil and gas plant.

Component
MOC (Vol% O2)
Hydrogen
4.0
Acetylene
6.2
Methane (C1)
12.0
Ethane (C2)
11.2
Ethylene (C2=)
9.9
Propane (C3)
11.6
Propylene (C3=)
11.5
Butane (C4)
12.3
1-Butene (C4=)
11.0
Pentane (C5)
11.8
Hexane (C6)
11.8
Benzene (Bz)
11.5
Carbon Disulfide
5.0

Base on this principle, a flare header is purged with hydrocarbon (i.e. fuel gas ) to evacuate air that ingressed via flare tip and stack in order to ensure quantity of oxygen level in the flare system is always below minimum oxygen concentration (MOC).

MOC For Flare Purge
From above table, you may noticed that MOC for majority of components are equal to or more than 10 vol% except Hydrogen (H2), Acethylene and Carbon Disulfide (CS2). It is recommended MOC of 6 vol% for flare purging design with 4 vol% as design margin. One shall remember plant releasing large amount of Hydrogen shall use lower MOC with margin i.e. 2 vol%. One of the example is Hydrogenation unit in Refinery plant.

Related Topic

Wednesday, June 20, 2007

Nitrogen Purging - What are the factors you need to consider ?


Nitrogen purging is common in Oil & Gas, refinery, Petrochemical & Chemical plant. Some factors you may need to consider...
Methodology
Generally Nitrogen purging is conducted to evacaute oxygen content to a level low enough so that it has no effect to process fluid. If you need to reduce to a VERY low oxygen level e.g. light water reactor, you may need to consider other methods.
N2 quality
You may need to assess you N2 quality. Plant N2 may contain 3% - 5% Oxygen, if your system need to go below 3%, obviously no way you can use plant nitrogen. You may need to use Liquified Nitrogen which may have >99.5% purity.
Criticallity of purging section
If you are purging reactor section, please always consider high purity N2.
Continuous versus Pressurise/depressurise
Large volume system better to apply pressurise/depresurise method. Plant Nitrogen supply pressure probably in the range of 8-10 barg. It may not be sufficient. You may take long time to purge your system. You may consider the Liquified Nitrogen.
Minimise N2 usage
If your system can take water after purging e.g. amine system, you may consider to fill the system with water and follow by N2 purging (replacing the water content). This significantly reduce N2 consumption.
Safety
"Nitrogen is a notorious and stealth killer!". Try to limit the volume of purging section filled with N2. The discharge section should be directed to minimum manning area.
Noise level
Normally pressurise / depressurise method will create high pitch and high SPL noise. You may need to comply to authority requirements during purging.








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