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Co2 being captured will be injected in the reservior. The injection can be as high as 300-400 atm which is higher than the critical pressure of Co2.
How does Co2 in Supercritical looks like ?
The following image (running in sequence) shows liquid Co2 under pressure boiled and transform itself to supercritical fluid (SCF).

During precommissioning / commisioning phase, some system may required acid cleaning in order to remove grease, oil, corrosion stuff, welded slag, etc. Through acid cleaning, it may oxidize metal surface layer so that it form a strong and corrosion resistance layer for vessel protection. Sometime, it called passivation and "cooking a vessel" in layman term.

How to Design a Shell-and-Tube Heat Exchanger

Heat Transfer to or from a Fluid Flowing Through a Tube

For a vent stack, at least 3 main criteria shall be met :
i) Toxic / flammable component well dispersed and meeting health and safe level during Normal operation (Nor. Op.) and emergency situation (Emer. Op.). very much subject to components / species in vent gas. Local regulations will probably indicate the limits of various components. In additional, Material Safety Datasheet (MSDS) will probably indicate the limits. PHAST, FRED, etc can be used for dispersion study.