Friday, April 9, 2010

Overview of Chemical Reaction Engineering

Every industrial chemical process is designed to produce economically a desired
product from a variety of starting materials through a succession of treatment
steps. Figure 1.1 shows a typical situation. The raw materials undergo a number
of physical treatment steps to put them in the form in which they can be reacted
chemically. Then they pass through the reactor. The products of the reaction
must then undergo further physical treatment-separations, purifications, etc.-
for the final desired product to be obtained.
Design of equipment for the physical treatment steps is studied in the unit
operations. In this book we are concerned with the chemical treatment step of
a process. Economically this may be an inconsequential unit, perhaps a simple
mixing tank. Frequently, however, the chemical treatment step is the heart of
the process, the thing that makes or breaks the process economically.

Design of the reactor is no routine matter, and many alternatives can be
proposed for a process. In searching for the optimum it is not just the cost of
the reactor that must be minimized. One design may have low reactor cost, but
the materials leaving the unit may be such that their treatment requires a much
higher cost than alternative designs. Hence, the economics of the overall process
must be considered.
Reactor design uses information, knowledge, and experience from a variety
of areas-thermodynamics, chemical kinetics, fluid mechanics, heat transfer,
mass transfer, and economics. Chemical reaction engineering is the synthesis of
all these factors with the aim of properly designing a chemical reactor.
To find what a reactor is able to do we need to know the kinetics, the contacting
pattern and the performance equation. We show this schematically in Fig. 1.2.

Figure 1.1 Typical chemical process.



Figure 1.2 Information needed to predict what a reactor can do.

Much of this book deals with finding the expression to relate input to output
for various kinetics and various contacting patterns, or

output = f [input, kinetics, contacting]

This is called the performance equation. Why is this important? Because with
this expression we can compare different designs and conditions, find which is
best, and then scale up to larger units.



source: Octave Levenspiel

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